It took 25.06 0.05 mL of a sodium hydroxide solution to titrate a 0.4016-g sample of KHP. Calculate the concentration and uncertainty in the concentration of the sodium hydroxide solution. Neglect any uncertainty in the mass.
Uncertainty in the concentration of sodium
Full Answer Section
Concentration of NaOH:
- Molar mass of KHP (potassium hydrogen phthalate) = 204.22 g/mol
- Volume of NaOH solution used (in liters) = 25.06 mL * (1 L / 1000 mL) = 0.02506 L
- Mass of KHP = 0.4016 g
- Moles of KHP (assuming KHP reacts 1:1 with NaOH) = mass of KHP / molar mass of KHP = 0.4016 g / 204.22 g/mol = 0.00196 mol
- Concentration of NaOH (in mol/L) = moles of KHP / volume of NaOH solution = 0.00196 mol / 0.02506 L = 0.0785 mol/L
Uncertainty in Concentration:
- Uncertainty in volume (assuming 0.05 mL represents standard deviation) = 0.05 mL * (1 L / 1000 mL) = 5.00 * 10^-5 L
- Using propagation of error, the uncertainty in concentration can be estimated as:
- uncertainty_concentration = concentration_naoh * (uncertainty_volume / volume_naoh)
- uncertainty_concentration = 0.0785 mol/L * (5.00 * 10^-5 L / 0.02506 L) = 0.0002 mol/L
Results:
- Concentration of NaOH: 0.0785 mol/L
- Uncertainty in concentration: ±0.0002 mol/L
The concentration of the sodium hydroxide solution is 0.0785 mol/L with an uncertainty of ±0.0002 mol/L. This uncertainty is likely due to the uncertainty in the measured volume of the NaOH solution.